Magnesium aluminide is an intermetallic, intermetallic compound of magnesium and aluminium. Common phases (molecular structures) include the beta phase (Mg₂Al₃) and the gamma phase (Mg₁₇Al₁₂), which both have cubic crystal system, cubic crystal structures. Magnesium aluminides are important constituents of 5XXX aluminium alloys (aluminium-magnesium) and magnesium-aluminium alloys, determining many of their engineering properties. Due to the advantage of low density and being strong, magnesium aluminide is important for aircraft engines. MgAl has also been investigated for use as a reactant to produce metal hydrides in hydrogen storage technology. Like many intermetallics, MgAl compounds often have unusual stoichiometry, stoichiometries with large and complex crystal structure, unit cells.

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* Alloys Aluminides Magnesium compounds {{inorganic-compound-stub